/give @p minecraft:player_head[
minecraft:profile={
properties: [{
name: "textures",
value: "eyJ0ZXh0dXJlcyI6eyJTS0lOIjp7InVybCI6Imh0dHBzOi8vdGV4dHVyZXMubWluZWNyYWZ0Lm5ldC90ZXh0dXJlL3VuZGVmaW5lZCJ9fX0="
}]
}
]
A character with green eyes, wearing a black robe and white shoes.
A character with green eyes and a black hood, wearing a white belt and a white shirt.
put what hair, face etc that you want